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Here's an example of a table (I put % in so that the wiki wouldn't format this stuff.):
%\begin{table}[h!]
%\begin{center}
%\begin{tabular}{ |c || c | c | c | c |}
%\hline
%Molecule & $\omega_e$ & $\omega_ex_e$ & $B_e$ & $\alpha_e$ \\ \hline %\hline
%\textbf{D$_2$} & 3118.4 & 64.09 & 30.429 & 1.0492 \\ \hline
%\textbf{H$_2$} & 4395.2 & 117.99 & 60.800 & 2.993 \\ \hline
%\end{tabular}
%\end{center}
%\caption{\textit{Deuterium and Hydrogen Constants} This table presents the values of the constants needed to calculate the energies of the molecular states as detailed above. All values are for the ground electronic state, and units for all entries are wavenumbers (cm$^{-1}$). All values are from Table 39 of the appendix of Herzberg \cite{herzberg}.}
%\label{table:appendix}
%\end{table}
Here you can change the alignment of the text in each column next to {tablular}. Each column is represented by a letter - r, l, and c for right, left, or centered text.
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